An Abnormal Reaction of N- (2,4-dinitrophenyl)-L-proline with Thionyl Chloride

被引：0
|
作者：
Zhi Bin XU
机构：
来源：
ChineseChemicalLetters | 2003年 / 02期
关键词：
L-Proline; 1-fluoro-2; 4-dinitrobenzene(FDNB); N-(2; 4-dinitrophenyl)-4-amino-n-butyl aldehyde;
D O I：
暂无
中图分类号：
O625 [芳香族化合物];
学科分类号：
摘要：
N- (2,4-Dinitrophenyl)-4-amino-n-butyl aldehyde 3 was obtained with high yield of 80% when N- (2,4-dinitrophenyl)-L-proline 1 reacted with SOCl2 at room temperature. However, the anticipated product N- (2,4-dinitrophenyl)-tetrahydropyrrolyl-2- (4-methylthiophenyl) ketone 2 did not be produced. The mechanism was discussed in this article.
引用
收藏
页码：133 / 134
页数：2
相关论文
共 50 条
  • [1] An abnormal reaction of N-(2,4-dinitrophenyl)-L-proline with thionyl chloride
    Xu, ZB
    Guo, ZR
    CHINESE CHEMICAL LETTERS, 2003, 14 (02) : 133 - 134
  • [2] Reversal of elution order of N-(2,4-dinitrophenyl)-proline and N-(2,4-dinitrophenyl)-serine in HPLC by BSA chiral stationary phase
    Wang, Qiuyun
    Xiong, Yajin
    Lu, Baozhu
    Fan, Jun
    Zhang, Sheng
    Zheng, Shengrun
    Zhang, Weiguang
    JOURNAL OF SEPARATION SCIENCE, 2013, 36 (08) : 1343 - 1348
  • [3] SYNTHESIS AND REACTIONS OF N-(2,4-DINITROPHENYL)-ACETOHYDRAZONYL CHLORIDE
    TEWARI, RS
    PARIHAR, P
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1983, 60 (10) : 961 - 963
  • [4] N-(2,4-dinitrophenyl)dehydroabietylamine
    Qiu, Fei
    Hong, Min
    Jiang, Dawei
    Zhu, Jin
    Huang, Lequn Lee
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O889 - U2354
  • [5] ON N-(2,4-DINITROPHENYL) PHTHALIMIDE
    BECKWITH, AL
    MILLER, J
    AUSTRALIAN JOURNAL OF SCIENTIFIC RESEARCH SERIES A-PHYSICAL SCIENCES, 1952, 5 (04): : 786 - 789
  • [6] REACTION-KINETICS AND MECHANISM OF N-(2,4-DINITROPHENYL)PYRIDINIUM CHLORIDE WITH ANILINE
    KAVALEK, J
    STERBA, V
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1973, 38 (11) : 3506 - 3510
  • [7] BASE CATALYSIS IN REACTION OF N-(2,4-DINITROPHENYL)PYRIDINIUM CHLORIDE WITH ANILINE AND N-METHYLANILINE
    KAVALEK, J
    BARTECEK, A
    STERBA, V
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1974, 39 (07) : 1717 - 1721
  • [8] Reductive cyclization of N-(2,4-dinitrophenyl)pyridinium chloride by tin(II) chloride
    Begunov, RS
    Ryzvanivich, GA
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 2004, (09): : 1407 - 1408
  • [9] Reductive cyclization of N-(2,4-dinitrophenyl)pyridinium chloride by tin(II) chloride
    Begunov R.S.
    Ryzvanovich G.A.
    Chemistry of Heterocyclic Compounds, 2004, 40 (9) : 1224 - 1225
  • [10] S-]N AND N-]S REVERSE REARRANGEMENT OF S-(2,4-DINITROPHENYL)CYSTEINES AND N-(2,4-DINITROPHENYL)CYSTEINES
    KONDO, H
    MORIUCHI, F
    SUNAMOTO, J
    JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (07): : 1333 - 1336
12345