UV-Vis Spectroscopy Study on Interaction between Microperoxidase-11 and Pr Ion Under Acid Rain Stress

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作者
吉红念
黄晓华
周青
陆天虹
机构
关键词
rare earths; praseodymium; microperoxidase-11; UV-Vis spectroscopy; acid rain stress; antagonistic effect;
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O657.3 [光化学分析法(光谱分析法)];
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摘要
Interaction between rare earth ion praseodymium (Pr(Ⅲ)) and MP11 with/without hydrogen ion (H +) in different media( aqueous, phosphate buffer, physiological condition) were studied by UV Vis spectroscopy. All the results indicate that Pr(Ⅲ) interacts with MP11, increasing the non planarity of porphyrin periphery, leading MP11 to form two conformations when titrated by Pr(Ⅲ). Excessive Pr(Ⅲ) acts as a contaminant in living organism. H + and Pr(Ⅲ) have antagonistic effect on MP11, suggesting that at suitable concentration under physiological conditions, Pr(Ⅲ) can be used as biomodulator in protecting plants from acid rain stress or in rehabilitating the harm.
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页码:541 / 546
页数:6
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