CRYSTAL STRUCTURE OF Mo3(μ3-O) (μ-S2) 3 [S2P(OEt)2]3I

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作者
Shang Maoyu Huang Jinling and Lu JiaxiFujian Institute of Research on the Structure of Matter
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Mo; S2P; Ho; S2; OEt; CRYSTAL STRUCTURE OF Mo3;
D O I
10.14102/j.cnki.0254-5861.1984.01.005
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摘要
Mr=1178.9, monoclinic, P21/n, a=16.570(2), b=12.370(1), c=20.007(2) A,β=99.97(1)°, V=4039.0A3, Z=4, Dx=1.938 Mgm-3, λ(MoKα)=0.7107A, μ(MoKα)=23.96 F(000)=2296, room temperature. Final R value=0.047 for 4387 unique observed reflections. It consists of neutral mono-oxo-capped trinuclear molybdenum cluster molecules with an average Mo-Mo bond length of 2.626(4)A and an average Mo-0 bond length of 2.036(2)8.
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页码:17 / 20
页数:4
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