CH2（3B1）与NO的基元化学反应研究

被引：5

作者：

杨继新

苏红梅

毛文涛

钟晋贤

孔繁敖

机构：

[1] 中国科学院生态环境研究中心!北京

[2] 不详

[3] 中国科学院化学研究所分子反应动力学国家重点实验室!北京

来源：

物理化学学报 | 1999年 / 07期

关键词：

CH2(■3B1); 态-态反应; TR-FTIR; NO;

D O I：

暂无

中图分类号：

O641 [结构化学];

学科分类号：

摘要：

The reaction of methylene radicals in their 3 B1 electronic ground state with molecular NO was studied. Pure CH2(X 3 B1 ) radicals were prodced by UV photolysis of ketene at 351 nm.The products were measured by Time-Resolved Fourier Transform Infrard (TR-FTIR) spectrometer. CO.OH .NH2 and HOCN or its isomer HNCO were found as primary prodcts and several possible channels of this reaction were suggested.

引用

页码：643 / 646

页数：4