THE INTRAMOLECULAR AROMATIC-RING STACKING INTERACTION OF MIXED LIGAND PALLADIUM（Ⅱ）COMPLEXES Ⅲ.STUDIES ON THE Pd2+-A-UTP4-SYSTEMS BY HNMR

被引：0

作者：

Yu Qiu GONG Hong Liang SUN Department of Chemistry

机构：

来源：

Chinese Chemical Letters | 1991年 / 07期

关键词：

SYSTEMS BY HNMR; THE INTRAMOLECULAR AROMATIC-RING STACKING INTERACTION OF MIXED LIGAND PALLADIUM; STUDIES ON THE Pd; COMPLEXES; A-UTP;

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摘要：

The intramolecular aromatic-ring stacking interaction of mixed-ligand complex Pd（A）(UTP);in the system pd;-A-UTP;has been determinedby;HNMR,where A=1,10-phenanthroline（phen）,2,2’-bipyridyl（bpy）and DL-tryptophan（trp;）;UTP;=uridine 5-triphosphate.The result indicates that itis the partial stacking between the uracil ring of UTP;and the heterocyclicring of A that makes H（5）,H（6）and H（1’）in the UTP;shift upfield signifi-cantly.Accordingly,the order of aromatic-ring interaction in the mixed-ligand complex has been obtained as follows:Pd（phen）(UTP);（?）Pd（bpy）(UTP);Pd（trp）(UTP);.

引用

页码：593 / 594

页数：2

共 28 条

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ChineseScienceBulletin, 1997, (14) : 1172 - 1175
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[5] THE INTRAMOLECULAR AROMATIC-RING STACKING INTERACTION OF THE TERNARY MIXED-LIGAND COMPLEXES - STUDY OF PD2+- HETEROCYCLIC RING BASE-NUCLEOTIDE SYSTEM BY POTENTIOMETRIC PH TITRATION
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[7] THE INTRAMOLECULAR AROMATIC-RING STACKING INTERACTION OF THE TERNARY MIXEDLIGAND COMPLEXES:STUDY OF Pd2+-HETEROCYCLIC RING BASE-NUCLEOTIDE SYSTEM BY POTENTIOMETRIC pH TITRATION
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CHINESE JOURNAL OF CHEMISTRY, 1998, 16 (04) : 356 - 362

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