Boron removal from metallurgical grade silicon by slag refining based on GA-BP neural network

In order to investigate the boron removal effect in slag refining process,intermediate frequency furnace was used to purify boron in SiO-CaO-NaAlF-CaSiOslag system at 1,550℃,and back propagation(BP) neural network was used to model the relationship between slag compositions and boron content in SiO-CaO-NaAlF-CaSiOslag system.The BP neural network predicted error is below 2.38 %.The prediction results show that the slag composition has a significant influence on boron removal.Increasing the basicity of slag by adding CaO or NaAlFto CaSiO-based slag could contribute to the boron removal,and the addition of NaAlFhas a better removal effect in comparison with the addition of CaO.The oxidizing characteristic of CaSiOresults in the ineffective removal with the addition of SiO.The increase of oxygen potential(pO)in the CaO-NaAlF-CaSiOslag system by varying the SiOproportion can also contribute to the boron removal in silicon ingot.The best slag composition to remove boron was predicted by BP neural network using genetic algorithm(GA).The predicted results show that the mass fraction of boron in silicon reduces from 14.0000 × 10to0.4366×10after slag melting using 23.12 % SiO-10.44 % CaO-16.83 % NaAlF-49.61 % CaSiOslag system,close to the experimental boron content in silicon which is below 0.5×10.