(火积)理论在热功转换过程中的应用探讨

被引:18
作者
程雪涛
梁新刚
机构
[1] 清华大学工程力学系
关键词
(火积)损失; 熵产; Carnot循环; 热功转换过程;
D O I
暂无
中图分类号
O414.1 [热力学];
学科分类号
080701 ;
摘要
分析和讨论了(火积)理论在热功转换过程的应用及其局限性.对Carnot循环的分析表明,Carnot循环中系统的(火积)是平衡的,但(火积)和熵之间不存在dG=T2dS这样的联系.对于一般热力学过程,分析表明,在热量传递到内可逆循环中间接对外做功时,现有的(火积)理论可用于系统的分析.讨论了热功转换过程分析中(火积)理论与熵理论的不同.分析表明,两个理论的分析角度及优化输出功的前提条件是不同的.熵产从可用能损失的角度分析热功转换过程,而(火积)理论则从热量势能消耗的角度.当输入系统的可用能给定或者输入系统的热量及热量进、出系统的热力学力给定时,熵产最小化对应于输出功最大;对于(火积)理论,则当输入系统的热量及热量进、出系统的温度给定时,最大(火积)损失对应于最大输出功.同时,它们各自均有局限性.当相应的前提条件不满足时,最大(火积)损失或最小熵产可能不与最大输出功相对应.
引用
收藏
页码:40 / 47
页数:8
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