Transition metal-catalyzed cross-coupling reactions of N-aryl-2-aminopyridines

被引：1

作者：

Doraghi, Fatemeh ^{[1
]}

Rezainia, Lina ^{[2
]}

Morshedsolouk, Mohammad Hossein ^{[1
,2
]}

Navid, Hamed ^{[2
]}

Larijani, Bagher ^{[1
]}

Mahdavi, Mohammad ^{[1
]}

机构：

[1] Univ Tehran Med Sci, Endocrinol & Metab Clin Sci Inst, Endocrinol & Metab Res Ctr, Tehran, Iran

[2] Univ Tehran, Coll Sci, Sch Chem, Tehran, Iran

来源：

RSC ADVANCES | 2025年 / 15卷 / 02期

关键词：

C-H ACTIVATION; ANNULATION; FUNCTIONALIZATION; AMINATION; ALKYNES; ACCESS; ARENES;

D O I：

10.1039/d4ra08384a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Due to the presence of the pyridyl directing group, N-aryl-2-aminopyridines can quickly form stable complexes with metals, leading to cyclization and functionalization reactions. A large number of N-heterocycles and nitrogen-based molecules can be easily constructed via this direct and atom-economical cross-coupling strategy. In this review, we have highlighted the transformations of N-aryl-2-aminopyridines in the presence of various transition metal catalysts, such as palladium, rhodium, iridium, ruthenium, cobalt and copper.

引用

页码：1134 / 1151

页数：18

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