First calculation of Q-e values for polymer radicals

Using our recently derived intrinsic Q-e scheme, unknown reactivity ratios of monomer pairs can be expressed without arbitrariness using only the reactivity ratios of the target and reference monomers, resulting in a high prediction accuracy of reactivity ratios. Furthermore, the Q-e values of polymer radicals and monomers can be calculated separately for the first time. In this paper, we introduce the intrinsic Q-e scheme, followed by the calculation of Q-e values for monomers and radicals.