The synthesis, characterization, and thermal properties of a titanium (III) amidinate compound and its potential as a single chemical vapor deposition precursor for N/C-doped TiO2 film

被引：0
|
作者：
Zhang, Y. [1 ]
Ju, Z. [1 ]
Yao, C. [1 ]
Liu, L. [1 ]
Zhang, X. [1 ]
Xing, J. [1 ]
Cheng, L. [2 ]
机构：
[1] Xuchang Univ, Inst Surface Micro & Nano Mat, Coll Chem & Mat Engn, Key Lab Micronano Mat Energy Storage & Convers Hen, Xuchang 461000, Henan, Peoples R China
[2] Hefei ADChem Semitech co Ltd, Hefei 230000, Peoples R China
来源：
DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES | 2024年 / 19卷 / 04期
关键词：
Synthesis; Titanium(III) amidinate; CVD; Precursor; N/C-doped TiO2 film; VISIBLE-LIGHT; THIN-FILMS; COMPLEXES; PHOTOCATALYST; PERFORMANCE; COATINGS; ROUTE; ACID; ME;
D O I：
10.15251/DJNB.2024.194.1459
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
A titanium(III) amidinate compound had been successfully obtained using a salt elimination reaction between TiCl3(3THF) and [Li(iPr-nBuAMD)] in a 65% yield, and the characterization of the compound was conducted using various characterization methods. The reported compound's thermal performances were studied through thermal gravimetric analysis (TGA), and the result indicated that the reported titanium(III) amidinate compound exhibited a suitable volatility, high thermal stability, and sufficient vapor pressure. Furthermore, film material deposit was performed in a CVD reactor under low pressure, and a N/C-doped TiO2 film was successfully deposited.
引用
收藏
页码：1459 / 1469
页数：11
相关论文
共 11 条
  • [1] In situ synthesis of mesoporous C-doped TiO2 single crystal with oxygen vacancy and its enhanced sunlight photocatalytic properties
    Lu, Jing
    Wang, Yong
    Huang, Jianfeng
    Fei, Jie
    Cao, Liyun
    Li, Cuiyan
    DYES AND PIGMENTS, 2017, 144 : 203 - 211
  • [2] Synthesis of highly efficient C-doped TiO2 photocatalyst and its photo-generated charge-transfer properties
    Li, Haiyan
    Wang, Dejun
    Fan, Haimei
    Wang, Ping
    Jiang, Tengfei
    Xie, Tengfeng
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 354 (01) : 175 - 180
  • [3] Facile synthesis of N-doped TiO2 nanoparticles by a modified polymeric precursor method and its photocatalytic properties
    Soares, Gabriela B.
    Bravin, Bruno
    Vaz, Carlos M. P.
    Ribeiro, Caue
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2011, 106 (3-4) : 287 - 294
  • [4] Photoelectrochemical and structural properties of TiO2 and N-doped TiO2 thin films synthesized using pulsed direct current plasma-activated chemical vapor deposition
    Randeniya, L. K.
    Bendavid, A.
    Martin, P. J.
    Preston, E. W.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (49): : 18334 - 18340
  • [5] Analysis of mechanical properties of N2 in situ doped polycrystalline 3C-SiC thin films by chemical vapor deposition using single-precursor hexamethyildisilane
    Kim, Kang-San
    Han, Ki-Bong
    Chung, Gwiy-Sang
    PHYSICA B-CONDENSED MATTER, 2010, 405 (02) : 513 - 516
  • [6] Synthesis and characterization of TiO2@C core-shell nanowires and nanowalls via chemical vapor deposition for potential large-scale production
    Liu, Hao
    Zhang, Yong
    Li, Ruying
    Cai, Mei
    Sun, Xueliang
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2012, 367 : 115 - 119
  • [7] Synthesis, Characterization, and Thermal Properties of Chlorine-Containing 1,1,2,2-Tetraaminodisilanes and Their Potential as Chemical Vapor Deposition Precursors for Silicon Nitride Films
    Du, Liyong
    Chu, Wenxiang
    Miao, Hongyan
    Wang, Dawei
    Xu, Chongying
    Ding, Yuqiang
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (19) : 3205 - 3211
  • [8] Characterization and one-step synthesis of Hydroxyapatite-Ti(C,N)-TiO2 composite coating by cathodic plasma electrolytic saturation and accompanying electrochemical deposition on titanium alloy
    Huang, Jiewen
    Fan, Xinmin
    Xiong, Dangsheng
    Li, Jianliang
    Zhu, Heguo
    Huang, Min
    SURFACE & COATINGS TECHNOLOGY, 2017, 324 : 463 - 470
  • [9] Studies on Synthesis and Characterization of a Chemically Deposited Nanostructured Thin Film of Ternary Compound Silver Bismuth Sulfide (AgBi2S3) onto n-Type Wide Band Gap Semiconducting Titanium Dioxide (TiO2)
    Padwal, Sachin
    Wagh, Rahul
    Thakare, Jivan
    Patil, Rajendra
    JOM, 2023, 75 (07) : 2480 - 2488
  • [10] Studies on Synthesis and Characterization of a Chemically Deposited Nanostructured Thin Film of Ternary Compound Silver Bismuth Sulfide (AgBi2S3) onto n-Type Wide Band Gap Semiconducting Titanium Dioxide (TiO2)
    Sachin Padwal
    Rahul Wagh
    Jivan Thakare
    Rajendra Patil
    JOM, 2023, 75 : 2480 - 2488
12