Gold(I)-Catalyzed Intramolecular C(sp3)-H Bond Functionalization

被引：0
|
作者：
Miguelez, Ruben
Arto, Omar
Rodriguez-Arias, Carlos
Barrio, Pablo [1 ]
机构：
[1] Univ Oviedo, Dept Quim Organ & Inorgan, Ave Julian Claveria 8, Oviedo 33006, Spain
来源：
SYNTHESIS-STUTTGART | 2025年 / 57卷 / 06期
关键词：
gold-catalysis; C-H functionalization; cyclization; carbene insertion; 1,5]-hydride shift; vinyl cation; C-H BOND; GOLD-CATALYZED SYNTHESIS; RETRO-BUCHNER REACTION; UNACTIVATED C(SP(3))-H BONDS; ASYMMETRIC ALDOL REACTION; SUBSTITUTED ARYL ALKYNES; FACE-SELECTIVE PLATINUM; INSERTION REACTIONS; STEREOSELECTIVE CONSTRUCTION; CYCLOISOMERIZATION REACTIONS;
D O I：
10.1055/a-2389-7434
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The merger of two of the most rapidly growing fields in catalysis, namely gold-catalysis and C-H activation/functionalization has resulted in major breakthroughs, affording unprecedented transformations. This review covers the most relevant contributions in this field during the last 10 years, restricted to the intramolecular functionalization of C(sp(3))-H bonds.
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收藏
页码：1138 / 1152
页数：15
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