We make two contributions pertaining to the study of the quantum chromatic numbers of small graphs. Firstly, in an elegant paper, Mancinska and Roberson [Baltic Journal on Modern Computing, 4(4), 846-859, 2016] gave an example of a graph G14 on 14 vertices with quantum chromatic number 4 and classical chromatic number 5, and conjectured that this is the smallest graph exhibiting a separation between the two parameters, as measured by the number of vertices. We describe a computer-assisted proof of this conjecture, thereby resolving a longstanding open problem in quantum graph theory. Our second contribution pertains to the study of the rank-r quantum chromatic numbers. While it can now be shown that for every r, chi q and chi(r) q are distinct, few small examples of separations between these parameters are known. We give the smallest known example of such a separation in the form of a graph G21 on 21 vertices with chi q(G21) = chi(2) q(G21) = 4 and xi(G21) = chi(1) q (G21) = chi(G21) = 5. The previous record was held by a graph Gmsg on 57 vertices that was first considered in the aforementioned paper of Mancinska and Roberson and which satisfies chi q(Gmsg) = 3 and chi(1) q (Gmsg) = 4. In addition, G21 provides the first provable separation between the parameters chi(1) q and chi(2) q . We believe that our techniques for constructing G21 and lower bounding its orthogonal rank could be of independent interest.