We present a pilot study where spectral unmixing is applied to hyperspectral images captured in a controlled environment with a threefold purpose in mind: validation of our experimental setup, of the data processing pipeline, and of the usage of spectral unmixing algorithms for the aforementioned research avenue. Results from this study show that classical techniques such as VCA and FCLS can be used to distinguish between plastic and nonplastic materials, but struggle significantly to distinguish between spectrally similar plastics, even in the presence of multiple pure pixels.