CO2 to Methanol Conversion: A Bibliometric Analysis with Insights into Reaction Mechanisms, and Recent Advances in Catalytic Conversion

The rising levels of atmospheric carbon dioxide (CO2) necessitate urgent and effective strategies for its capture and utilization. Among the various CO2 valorization pathways, the conversion of CO2 into methanol has gained considerable attention due to its dual role in reducing greenhouse gas emissions and serving as a renewable fuel and chemical feedstock. This review uniquely combines bibliometric analysis of 13,289 peer-reviewed publications (2012-2023) with an evaluation of Cu-based catalyst advancements, addressing critical gaps in the literature. A bibliometric analysis highlights the key trends, collaborations, and research gaps in the field. Among the catalytic systems, noble metals, though highly active, are uneconomical for large-scale applications, while non-noble metals, such as nickel, exhibit limited activity due to undesired reaction pathways. In comparison, Cu-based catalysts overcome these challenges by offering a balance of activity, selectivity, and cost-effectiveness. Special emphasis is placed on the CO2 to methanol conversion pathways, with insights into thermodynamic constraints, emerging solutions, and potential directions for future research. By consolidating the current state of knowledge, this review identifies significant opportunities for advancing CO2 conversion technologies, particularly in methanol synthesis, positioning it as a promising strategy for sustainable carbon management and energy production.