Electrochemical and electrocatalytic properties of hemihexaphyrazine and its trinuclear cobalt complex

被引：0
|
作者：
Ivanov, Evgenii N. [1 ]
Berezina, Nadezhda M. [1 ]
Belyaev, Anton A. [1 ]
Kibireva, Yana E. [2 ]
Bazanov, Mikhail I. [1 ]
Islyaikin, Mikhail K. [1 ]
机构：
[1] Ivanovo State Univ Chem & Technol, Res Inst Macroheterocycles, Ivanovo 153000, Russia
[2] Russian Acad Sci, GA Krestov Inst Solut Chem, Ivanovo 153045, Russia
来源：
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2024年 / 28卷 / 09N10期
关键词：
macroheterocycles; hemihexaphyrazine; homotrinuclear cobalt complex; redox potentials; PORPHYRINS; HEMIPORPHYRAZINE; BEHAVIOR; NI;
D O I：
10.1142/S1088424624500500
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The electrochemical and electrocatalytic properties of hemihexaphyrazine and its trinuclear cobalt complex were studied by cyclic voltammetry. The possibility of detecting cationic and anionic forms of compounds in the process of polarization of electrodes in the region of potentials 0.5 divided by -1.5 V has been established. It is shown that the synthesized cobalt complex has a sufficiently high catalytic activity in the oxygen reduction reaction in an alkaline solution.
引用
收藏
页码：710 / 715
页数：6
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