Exsolved Cu-ZnO interfaces for methanol production from CO2 at atmospheric pressure

被引:2
|
作者
Soodi, Sanaz [1 ]
Cali, Eleonora [2 ]
Saini, Shailza [1 ]
Skinner, William S. [3 ]
Martin, Alex Martinez [1 ]
Kerherve, Gwilherm [3 ]
Mezzapesa, Marco Pietro [2 ]
Bensaid, Samir [2 ]
Payne, David J. [4 ]
Duyar, Melis S. [1 ]
Kousi, Kalliopi [1 ]
机构
[1] Univ Surrey, Sch Chem & Chem Engn, Guildford GU2 7XH, England
[2] Politecn Torino, Dept Appl Sci & Technol, Corso Duca Abruzzi 24, I-10129 Turin, Italy
[3] Imperial Coll London, Dept Mat, Exhibit Rd, London SW7 2AZ, England
[4] NEOM Educ Res & Innovat Fdn, Tabuk 496439136, Saudi Arabia
关键词
PARTICLE-SIZE; AU CATALYSTS; HYDROGENATION; OXIDES; COPPER; NANOPARTICLES; CONVERSION; MECHANISM; STATES;
D O I
10.1039/d4ta05812g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An intimate Cu-ZnO interface that allows for the conversion of CO2 to methanol even at atmospheric pressures was produced using the exsolution method. Detailed characterization and operando IR spectroscopy were employed to deconvolute the materials' properties that allow for this to happen.
引用
收藏
页数:10
相关论文
共 50 条
  • [1] Causation of catalytic activity of Cu-ZnO for CO2 hydrogenation to methanol
    Qi, Shi-Chao
    Liu, Xiao-Ying
    Zhu, Rong-Rong
    Xue, Ding-Ming
    Liu, Xiao-Qin
    Sun, Lin-Bing
    CHEMICAL ENGINEERING JOURNAL, 2022, 430
  • [2] A highly efficient Cu-ZnO/SBA-15 catalyst for CO2 hydrogenation to CO under atmospheric pressure
    Mao, Donglei
    Zhang, Jinxin
    Zhang, Heng
    Wu, Dongfang
    CATALYSIS TODAY, 2022, 402 : 60 - 66
  • [3] CO2 hydrogenation to methanol on Cu-ZnO/AlLaO with high activity and hydrothermal stability
    Li, Shaozhong
    Zhao, Xu
    Li, Yanxing
    Guo, Tan
    Zhu, Xiufang
    Hu, Yongke
    Shen, Gulou
    Wu, Mei
    Xiong, Jinyan
    APPLIED CATALYSIS A-GENERAL, 2025, 692
  • [4] Fine regulation of Cu-ZnO interfaces for enhanced CO2 hydrogenation to methanol by atomic layer depositing thin ZnO films on copper phyllosilicates
    Xia, Yegang
    Cha, Xingwen
    Yan, Xing
    Wang, Xueying
    Cai, Yanmei
    Tan, Kok Bing
    He, Jinxin
    Qiu, Ting
    Cai, Dongren
    Zhan, Guowu
    APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY, 2025, 361
  • [5] Combustion synthesis of Cu-ZnO catalyst for methanol production
    Yamaguchi, T
    Akiyama, T
    Yagi, J
    JOURNAL OF THE JAPAN INSTITUTE OF METALS, 1999, 63 (03) : 341 - 344
  • [6] Preserving the Active Cu-ZnO Interface for Selective Hydrogenation of CO2 to Dimethyl Ether and Methanol
    Cui, Xiaojing
    Yan, Wenjun
    Yang, Huanhuan
    Shi, Ying
    Xue, Yanfeng
    Zhang, He
    Niu, Yulan
    Fan, Weibin
    Deng, Tiansheng
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2021, 9 (07) : 2661 - 2672
  • [7] Effect of surface basicity over the supported Cu-ZnO catalysts on hydrogenation of CO2 to methanol
    Guo, Tan
    Guo, Qing
    Li, Shaozhong
    Hu, Yongke
    Yun, Shan
    Qian, Yunhua
    JOURNAL OF CATALYSIS, 2022, 407 : 312 - 321
  • [8] Effect of surface basicity over the supported Cu-ZnO catalysts on hydrogenation of CO2 to methanol
    Guo, Tan
    Guo, Qing
    Li, Shaozhong
    Hu, Yongke
    Yun, Shan
    Qian, Yunhua
    Journal of Catalysis, 2022, 407 : 312 - 321
  • [9] The Cu-ZnO synergy in methanol synthesis from CO2, Part 2: Origin of the methanol and CO selectivities explained by experimental studies and a sphere contact quantification model in randomly packed binary mixtures on Cu-ZnO coprecipitate catalysts
    Tisseraud, Celine
    Comminges, Clement
    Belin, Thomas
    Ahouari, Hania
    Soualah, Ahcene
    Pouilloux, Yannick
    Le Valant, Anthony
    JOURNAL OF CATALYSIS, 2015, 330 : 533 - 544
  • [10] Modified Cu-ZnO Catalysts Supported on the Mixture of ZnO and Zn-Al Oxide for Methanol Production via Hydrogenation of CO and CO2 Gas Mixture
    Song, Hyun-tae
    Kim, Hyun Dong
    Yang, Yu-jeong
    Seo, Jeong Min
    Choi, Ye-na
    Lee, Kwan-Young
    Moon, Dong Ju
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2024, 41 (05) : 1375 - 1389