Donor-Acceptor Complexes of the Lewis Acid Ga[N(C6F5)2]3 with Pyridine and Diethyl Ether

被引：0
|
作者：
Zavgorodnii, A. S. [1 ]
Kryukova, M. A. [1 ]
Timoshkin, A. Y. [1 ]
机构：
[1] St Petersburg State Univ, Inst Chem, St Petersburg, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2025年 / 66卷 / 02期
基金：
俄罗斯科学基金会;
关键词：
Lewis acids; donor-acceptor interaction; XRD; gallium decafluorodiphenylamide; pyridine; acetonitrile; SOLID-STATE; ACETONITRILE; SUPERACIDS;
D O I：
10.1134/S0022476625020040
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Donor-acceptor complexes of the Ga[N(C6F5)(2)](3) Lewis acid with pyridine and diethyl ether are prepared for the first time and characterized by single-crystal XRD. The gallium atom in the complexes has a trigonal-pyramidal environment with bond angles significantly differing from the tetrahedral ones, indicating a hindered character of the transformation of the Lewis acid from the free state to the geometry of the donor-acceptor complex.
引用
收藏
页码：251 / 260
页数：10
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