Polarization-Induced Internal Electric Field-Dominated S-Scheme KNbO3-CuO Heterojunction for Photoreduction of CO2 with High CH4 Selectivity

The polarization-induced internal electric field (IEF) in ferroelectric materials could promote photogenerated charge transfer across the heterojunction interface, but the effect of polarization-induced IEF on the mechanism of photogenerated charge transfer is ambiguous. In this study, a KNbO3-CuO heterojunction was synthesized by depositing copper oxide (CuO) onto KNbO3. Incorporating CuO broadens the light absorption of KNbO3, thereby enhancing the dissociation of the photogenerated charges. The results show that the polarization-induced IEF in KNbO3 determines that the charge transport mechanism in the KNbO3-CuO heterojunction follows the S-scheme. Owing to the S-scheme heterojunctions and efficient CO2 capture and activation by CuO, the CH4 production rate of KNbO3-CuO increased by nearly 26 times compared to KNbO3. Additionally, the CH4 selectivity of KNbO3-CuO could reach up to 97.80%. This research offers valuable insights into enhancing the photogenerated charge separation and constructing heterojunctions.