Negative longitudinal magnetoresistance in the Dirac semimetal PtSe2: Kondo effect and surface spin dynamics

The emergence of negative longitudinal magnetoresistance in the topologically nontrivial transition-metal dichalcogenide PtSe2 is studied. Low-T, high-mu 0H transport is performed for arbitrary field directions, and an analytical framework is established. The source of the negative longitudinal magnetoresistance is identified as the Kondo effect stemming from Pt vacancies contributing an uncompensated spin exclusively at the sample surface. The concentration of vacancies and the sample thickness are identified as tuning parameters. The findings are substantiated by density functional theory, which corroborates the proposed Pt-vacancy model.