Photocatalytic Composites Based on Biochar for Antibiotic and Dye Removal in Water Treatment

Many semiconductor photocatalysts are characterized by high photostability and non-toxicity but suffer from the limited excitation in the UV part of the spectrum and the fast recombination of the photogenerated electron-hole pairs. To improve the above properties, biochar-supported composite photocatalysts have recently attracted much attention. Compared with the pure photocatalyst, the biochar-enriched catalyst has superior specific surface area and high porosity, catalytic efficiency, stability, and recoverability. Biochar can be obtained from various carbon-rich plant or animal wastes by different thermochemical processes such as pyrolysis, hydrothermal carbonization, torrefaction, and gasification. The main features of biochar are its low price, non-toxicity, and the large number of surface functional groups. This paper systematically presents the latest research results on the method of preparation of various composites in terms of the choice of photoactive species and the source of biomass, their physico-chemical properties, the mechanism of the photocatalytic activity, and degradation efficiency in the treatment of organic contaminants (dyes and antibiotics) in an aquatic environment. Particular emphasis is placed on understanding the role of biochar in improving the photocatalytic activity of photoactive species.