Magnetic field enhanced discharge and water activation of atmospheric pressure plasma jet: effect of the assistance region and underlying physicochemical mechanism

Magnetic field-assistance holds the promise of becoming a new or complementary approach to enhance the efficiency of atmospheric pressure plasma jet (APPJ), but there is currently a lack of research on the effect of the assistance region between magnetic field and plasma on application of APPJ. Herein, using a 130 mT perpendicular magnetic field to assist APPJ in treating deionized water to prepare plasma activated water (PAW) as a model, we studied the effect of the magnetic field-assisted region on the performance of PAW produced by APPJ, and found that introducing a magnetic field could always enhance the performance of the prepared PAW with higher concentrations of H2O2, NO3-, and NO2- and lower concentrations of O3 and lower pH values, but this enhancement effect was related to the magnetic field-assisted region relative to the APPJ, where the optimized PAW performance was achieved when the magnetic field did not act on the jet tube wall (only assisting plasma plume). To reveal the underlying physicochemical mechanism behind the differences in the enhanced performance of PAW in different magnetic field-assisted regions, a plasma reaction network involving physical parameters and chemical products was considered. The results showed that the magnetic field-assisted region modulated the equilibrium between the confinement effect and the recombination loss of magnetized electrons, and subsequently altered the reactive species in PAW via a plasma reaction network mediated by electron density ne and electron excitation temperature Texc without remarkably changing the discharge intensity, discharge power, plasma plume, and gas temperature Tgas. These insights contribute to understanding the mechanism of the magnetic field-assisted region effect on APPJ, which provides guidance for optimizing discharge activity and promotes the development of applications.