ON THE POSSIBILITY OF MICROPHASE SEPARATION IN LIQUID CRYSTALLINE POLYMERS.

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Lipatov, Yu.S.
Tsukruk, V.V.
Shilov, V.V.
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BLOCK COPOLYMERS - CRYSTALS; LIQUID;
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The microphase structure of liquid crystalline polymers is considered in the framework of the thermodynamics of block copolymers. It is established that at a definite ratio of the flexible and rigid parts of mesogenic groups, phase separation takes place in liquid crystalline polymers. The polyesters of alkoxybenzoic acids with 12-16 carbon atoms in the aliphatic chain end of the mesogenic groups are considered to be two-phase polymeric systems.
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页码:75 / 77
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