The Use of Proton Magnetic Resonance in the Study of Complexones

被引:0
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作者
Kostromina, N.A. [1 ]
机构
[1] Institute of General and Inorganic Chemistry, Academy of Sciences of Ukrainian SSR, Kiev, Ukraine
关键词
Chemical stability - Magnetic resonance - Rate constants;
D O I
10.1070/RC1973v042n04ABEH002580
中图分类号
学科分类号
摘要
The available literature data for the protonation of complexones and the formation of their complexes with diamagnetic and paramagnetic ions are reviewed. A systematic and general account is given of studies on the equilibria and kinetics of complex formation and of the structures of the complexes. Typical PMR spectra of complexones and their metal complexes are presented; quantitative characteristics obtained from PMR data (chemical shifts, spin-spin coupling constants, stability constants, and reaction rate constants) are tabulated. The bibliography includes 99 references. © 1973 Turpion Ltd. All rights reserved.
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页码:261 / 277
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