PHASE EQUILIBRIA FOR MIXTURES CONTAINING VERY MANY COMPONENTS. DEVELOPMENT AND APPLICATION OF CONTINUOUS THERMODYNAMICS FOR CHEMICAL PROCESS DESIGN.

被引：0

作者：

Cotterman, Ronald L. ^{[1
]}

Bender, Rainer ^{[1
]}

Prausnitz, John M. ^{[1
]}

机构：

[1] Lawrence Berkeley Lab, Materials, & Molecular Research Div,, Berkeley, CA, USA, Lawrence Berkeley Lab, Materials & Molecular Research Div, Berkeley, CA, USA

来源：

Industrial & Engineering Chemistry, Process Design and Development | 1985年 / 24卷 / 01期

关键词：

HYDROCARBONS - Processing - LIQUIDS - NATURAL GAS - THERMODYNAMICS;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

For some multicomponent mixtures, where detailed chemical analysis is not feasible, the composition of the mixture may be described by a continuous distribution function of some convenient macroscopic property such as normal boiling point or molecular weight. To attain a quantitative description of phase equilibria for such mixtures, this work has developed thermodynamic procedures for continuous systems; that procedure is called continuous thermodynamics. To illustrate, continuous thermodynamics is used to calcualte dew points for natural-gas mixtures, solvent loss in a high-pressure absorber, and liquid-liquid phase equilibria in a polymer fractionation process. Continuous thermodynamics provides a rational method for calculating phase equilibria for those mixtures where complete chemical analysis is not available but where composition can be given by some statistical description.

引用

页码：194 / 203

共 6 条

[1] PHASE-EQUILIBRIA FOR MIXTURES CONTAINING VERY MANY COMPONENTS - DEVELOPMENT AND APPLICATION OF CONTINUOUS THERMODYNAMICS FOR CHEMICAL PROCESS DESIGN
COTTERMAN, RL
BENDER, R
PRAUSNITZ, JM
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1985, 24 (01): : 194 - 203
[2] DEVELOPMENT AND APPLICATION OF CONTINUOUS THERMODYNAMICS FOR COMPLEX CHEMICAL-EQUILIBRIA CALCULATIONS
KRAMARZ, J
WYCZESANY, A
CHEMICAL ENGINEERING SCIENCE, 1993, 48 (09) : 1665 - 1673
[3] CONTINUOUS THERMODYNAMICS FOR PHASE-EQUILIBRIUM CALCULATIONS IN CHEMICAL PROCESS DESIGN
COTTERMAN, RL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 201 : 37 - IEC
[4] PHASE-EQUILIBRIA IN MIXTURES OF GLYCERIDES AND CARBON-DIOXIDE AND APPLICATION OF CONTINUOUS THERMODYNAMICS TO MIXTURES OF RAPESEED OIL AND CARBON-DIOXIDE
KLEIN, T
SCHULZ, S
FLUID PHASE EQUILIBRIA, 1989, 50 (1-2) : 79 - 100
[5] MOLECULAR THERMODYNAMICS FOR FLUIDS AT LOW AND HIGH-DENSITIES .2. PHASE-EQUILIBRIA FOR MIXTURES CONTAINING COMPONENTS WITH LARGE DIFFERENCES IN MOLECULAR-SIZE OR POTENTIAL-ENERGY
COTTERMAN, RL
PRAUSNITZ, JM
AICHE JOURNAL, 1986, 32 (11) : 1799 - 1812
[6] Thermodynamics of mixtures containing a very strongly polar compound. Part I. Experimental phase equilibria (solid-liquid and liquid-liquid) for sulfolane+alkan-1-ols systems. Analysis of some mixtures including sulfolane in terms of disquac
Gonzalez, JA
Domanska, U
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (06) : 1034 - 1042

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