Coordination Chemistry and Raman Spectra of Acetylide Dianion

被引：0
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作者：
Guo, Guocong [1 ]
Lin, Shanhuo [1 ]
Zheng, Fakun [1 ]
Dong, Zhenchao [1 ]
Huang, Jinshun [1 ]
机构：
[1] State Key Lab. of Structrual Chem., Fujian Inst. Res. Struct. of Matter, Chinese Academy of Sciences, 350002 Fuzhou, China
来源：
| 2000年 / Science Press卷 / 20期
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摘要：
This paper shows the syntheses of double salts of silver acetylide with various soluble silver salts, investigations on the coordination modes of acetylide dianion and their Raman spectra, discussion of the relationship between the coordination chemistry of acetylide dianion and the bind mode of N2 molecule in the FeMoco factor of nitrogenase.The results present that the bind mode of N2 molecule inside the FeMoco factor of nitrogenase is more reasonable.
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