cis-dibromobis(dimethyl sulfoxide-S)-platinum(II) and trans-bis(dimethyl sulf-oxide-S)diiodoplatinum(II)

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Univ of Lund, Lund, Sweden ^{[1
]}

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来源：

Acta Crystallogr Sect C Cryst Struct Commun | / pt 8卷 / 1921-1924期

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Chemical bonds - Coordination reactions - Crystal structure - Isomerization - Mathematical techniques - Organometallics - Oxygen - Sulfur;

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摘要：

The Pt atom has a slightly distorted square-planar coordination in both title compounds, cis-[PtBr2(C2H6OS)2] and trans-[PtI2(C2H6OS)2], with the dimethyl sulfoxide ligands bonded via their S atoms. The bond distances to platinum in the bromo compound are Pt - Br 2.441 (1) and 2.447 (2), and Pt - S 2.254 (2) and 2.245 (2) angstrom, and in the centrosymmetric iodo complex are Pt - I 2.6111 (9) and Pt - S 2.289 (2) angstrom.

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