2,6-DIMETHYL-3-METHOXYPYRAZINE: A MICROBIOLOGICALLY-PRODUCED COMPOUND WITH AN OBNOXIOUS MUSTY ODOUR.

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Mottram, Donald S.
Patterson, Ronald L.S.
Warrilow, Elaine
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BACTERIOLOGY - CHROMATOGRAPHIC ANALYSIS - Gas - ORGANIC COMPOUNDS;
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An aerobic, gram-negative bacterium was apparently responsible for producing a foul odor in certain machine cutting fluid emulsions. Head-space volatiles from a culture broth of the bacterium were examined by gas chromatography as well as by combined gas chromatography-mass spectrometry, and the offending compound was narrowed down to either 2,5- or 2,6-dimethyl-3-methoxypyrazine. Both compounds were synthesized for comparison, and the 2,6-isomer was identified as the compound causing the odor.
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