SOLUBILITY OF NAPHTHALENE IN SOME ORGANIC SOLVENTS.

被引：0
|
作者：
Zaretskii, M.I.
Golub, V.B.
Podolyak, V.G.
Usyshkina, I.V.
Taits, S.Z.
Kononov, N.F.
机构：
来源：
Solid Fuel Chemistry | 1977年 / 11卷 / 05期
关键词：
MATHEMATICAL MODELS - SOLVENTS - Chemistry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In the reported experiments, the solubility of naphthalene in five organic solvents has been studied. A marked deviation from the ideality of the solutions formed by naphthalene with such power solvents as sulfolane, pyrrolid-2-one, hexametapol, and DEG has been found. A satisfactory correlation of the experimental results on the solubility of naphthalene with the values of the effective dipole moment has been obtained for some highly polar organic solvents. It is proposed to calculate the solubility of naphthalene in nonpolar solvents (parafinic hydrocarbons) by means of a modified Shreder equation using the values found for the differential heats of mixing at infinite dilution of the solid in the solvent. The applicability of the equation of regular solutions using the dispersion component of the solubility parameter for calculating the solubility of naphthalene in nonpolar and feebly polar solvents has been shown.
引用
收藏
页码：137 / 141
相关论文
共 50 条
  • [1] SOLUBILITY OF PROPYLENE IN ORGANIC SOLVENTS.
    Guzechak, O.Ya.
    Sarancha, V.N.
    Romanyuk, I.M.
    Yavorskaya, O.M.
    Churik, G.P.
    Journal of applied chemistry of the USSR, 1984, 57 (8 pt 1): : 1662 - 1665
  • [2] The solubility of phenanthrene in various organic solvents.
    Henstock, H
    JOURNAL OF THE CHEMICAL SOCIETY, 1922, 121 : 2124 - 2128
  • [3] The solubility of proteins and proteoses in aldehydes and other organic solvents.
    Cooper, EA
    Nicholas, SD
    BIOCHEMICAL JOURNAL, 1925, 19 (04) : 533 - 537
  • [4] The distribution of iodine between some organic solvents.
    Landau, M
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE--STOCHIOMETRIE UND VERWANDTSCHAFTSLEHRE, 1910, 73 (02): : 200 - 211
  • [5] Preparation of stannic iodide and its solubility in certain organic solvents.
    McDermott, FA
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1911, 33 : 1963 - 1965
  • [6] LOW-TEMPERATURE SOLUBILITY OF NAPHTHALENE IN SOME SOLVENTS
    PUGACH, VG
    KOROBCHANSKII, VI
    GREBENNIKOVA, SS
    DOBROVOLSKAYA, LE
    COKE & CHEMISTRY USSR, 1975, (07): : 30 - 31
  • [7] Concerning the solubility of coal in mixed solvents.
    Painter, PC
    Sobkowiak, M
    Gamble, V
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U858 - U858
  • [8] The solubility of ammonium bromide in alcoholic solvents.
    Bedwell, ME
    TRANSACTIONS OF THE FARADAY SOCIETY, 1943, 39 : 0205 - 0206
  • [9] Solubility of β-carotene in pure and mixed solvents.
    Kasprzycka-Guttman, T
    Treszczanowicz, A
    Treszczanowicz, T
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 220 : U205 - U205
  • [10] Theoretical models of solubility for organic solvents. A conceptual density functional theory approach
    Contreras, Renato
    Munoz-Espinoza, Jose
    Sanchez, Bruno
    JOURNAL OF MOLECULAR LIQUIDS, 2024, 403
12345