Study of the cointercalation of magnesium and cobalt chlorides into graphite

被引：0
|
作者：
Moundanga-Iniamy, M. [1 ]
Touzain, Ph. [1 ]
机构：
[1] Domaine Universitaire, Saint-Martin D'Heres, France
来源：
Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals | 1994年 / 244卷
关键词：
Cobalt chloride - Graphite intercalation compounds - Magnesium chloride - Reaction mechanisms;
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摘要：
The intercalation of magnesium chloride into graphite has been studied as a function of the temperature, in the presence of a chlorine gas. The second stage compound has been obtained at 580 °C, the average formula of which is C9MgCl2. By cointercalation of MgCl2 and CoCl2, at 600 °C, MgCl2/CoCl2 ratio equal to 4.5 and during ten days, the first stage compound C5.65(MgCl2)0.97(CoCl2)0.03 has been obtained. It only contains traces of CoCl2. A theoretical mechanism of this cointercalation is proposed.
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页码：65 / 70
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