Hydrogen sensing properties of a Pt-oxide-GaN Schottky diode

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作者
Tsai, Yan-Ying [1 ]
Lin, Kun-Wei [2 ]
Chen, Huey-Ing [3 ]
Liu, I-Ping [3 ]
Hung, Ching-Wen [1 ]
Chen, Tzu-Pin [1 ]
Tsai, Tsung-Han [1 ]
Chen, Li-Yang [1 ]
Chu, Kuei-Yi [1 ]
Liu, Wen-Chau [1 ]
机构
[1] Institute of Microelectronics, Department of Electrical Engineering, National Cheng-Kung University, No. 1, University Road, Tainan, 70101, Taiwan
[2] Department and Graduate Institute of Computer Science and Information Engineering, Chaoyang University of Technology, No. 168, Jifong East Road, Wufong Township, Taichung, 41349, Taiwan
[3] Department of Chemical Engineering, National Cheng-Kung University, No. 1, University Road, Tainan, 70101, Taiwan
来源
Journal of Applied Physics | 2008年 / 104卷 / 02期
关键词
The interesting hydrogen sensing properties of a Pt-oxide-GaN metal-oxide-semiconductor-type Schottky diode are comprehensively studied and demonstrated. In the hydrogen-containing environment; the shift in current-voltage curves and decrease in turn-on voltage are found to be caused by the lowering of Schottky barrier height. Also; the corresponding series resistance is decreased from 191.8 (in air) to 155.3 Ω (for a 9970 ppm H2/air gas) at 30C. As the carrier gas is replaced by a nitrogen gas; a significant variation of 0.32 V and 19.56 Ω in the turn-on voltage Von and series resistance Rs values; respectively; is obtained at 30C; even at an extremely low hydrogen concentration of 4.3 ppm H2/N2. Since the oxygen atoms will be dissolved on the Pt metal surface and react with hydrogen atoms by the formation of hydroxyl and water; the number of adsorbed hydrogen atoms on the Pt surface is reduced. Moreover; the shorter response time constant and the larger initial rate of current density variation are found even at room temperature. © 2008 American Institute of Physics;
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