Research Development of Magnesium Silicate Hydrate Cement

被引:0
|
作者
Song Q. [1 ]
Hu Y. [1 ]
Wang Q. [1 ]
Zhang J. [1 ]
Chen Y. [1 ]
机构
[1] College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an
关键词
Magnesium oxide; Magnesium silicate hydrate; Reaction mechanism; Silica fume;
D O I
10.14062/j.issn.0454-5648.2019.11.16
中图分类号
学科分类号
摘要
The reaction of MgO and soluble silica form magnesium silicate hydrate gel ((MgO)x-SiO2-(H2O)y, M-S-H). With different chemical compositions, poorly crystalline phases and sheet structures of silicon-oxy tetrahedron, and M-S-H is responsible for the compressive strength development. The formation rate of M-S-H depends on the activity of reactants, reactive MgO and silica fume are the common reactants. The reaction of mixture of MgO and silica fume with water is exothermic, and the hydration heat emission rate and quantity are associated with MgO reactivity. The weak alkalinity of solution of pastes shows a promising in potential applications as building materials. This review presented the reaction mechanisms, composition, pore solution chemistry, heat evolution, strength and workability, and analyzed the factors affecting the properties mentioned above. The effect of Mg2+ on C-S-H and Ca2+ on M-S-H calcium was summarized. In addition, the development of magnesium silicate hydrate cement in the future was also discussed. © 2019, Editorial Department of Journal of the Chinese Ceramic Society. All right reserved.
引用
收藏
页码:1642 / 1651
页数:9
相关论文
共 98 条
  • [1] Bowen N., Tuttle O., The system MgO-SiO<sub>2</sub>-H<sub>2</sub>O, Geol Soc Am Bull, 60, 3, pp. 439-460, (1949)
  • [2] Li Z., Reaction mechanisms and application study of MgO-SiO<sub>2</sub>-H<sub>2</sub>O cementitious system, (2010)
  • [3] Gartner E., Are there any practical alternatives to the manufacture of portland cement clinker?, J Chin Ceram Soc, 40, 1, pp. 61-68, (2012)
  • [4] Lakner K.S., Climate change: A guide to CO<sub>2</sub> sequestration, Science, 300, 5626, pp. 1677-1678, (2003)
  • [5] Ruiter D., Austrheim H., Formation of magnesium silicate hydrate cement in nature, J Geol Soc, 175, 2, pp. 308-320, (2018)
  • [6] Cole W.F., A crystalline hydrated magnesium silicate formed in the breakdown of a concrete sea wall, Nature, 171, 4347, pp. 354-355, (1953)
  • [7] Calvo J.L.G., Hidalgo A., Alonso C., Et al., Development of low-pH cementitious materials for HLRW repositories: Resistance against ground waters aggression, Cem Concr Res, 40, 8, pp. 1290-1297, (2010)
  • [8] Dauzeres A., Achiedo G., Nied D., Et al., Magnesium pertur-bation in low-pH concretes placed in clayey environment-solid characterizations and modeling, Cem Concr Res, 79, pp. 137-150, (2016)
  • [9] Jenn A., Mader U., Lerouge C., Et al., In situ interaction between different concretes and Opalinus clay, Phys Chem Earth, 70-71, pp. 71-83, (2014)
  • [10] Lerouge C., Gaboreau S., Grangeon S., Et al., In situ interactions between Opalinus clay and low alkali concrete, Phys Chem Earth, 99, pp. 3-21, (2017)