Polymerization of lactams. 99 Preparation of polyesteramides by the anionic copolymerization of Ε-caprolactam and Ε-caprolactone

被引：0
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作者：
Chromcová, Daniela [1 ]
Baslerová, Lucie [1 ]
Roda, Jan [1 ]
Brožek, Jiří [1 ]
机构：
[1] Department of Polymers, Institute of Chemical Technology, Prague, Technická 5, 16628 Prague 6, Czech Republic
来源：
European Polymer Journal | 2008年 / 44卷 / 06期
关键词：
Polyesteramides derived from the cyclic monomers Ε-caprolactam and Ε-caprolactone have been synthesized by the anionic polymerization and characterized. Ε-Caprolactam magnesium bromide was employed as unique initiator giving high yield of copolymer across the whole range of monomer concentrations at 150 °C. Owing to a variation of the content of ester and amide component in polyesteramide backbone a large variety of materials having diverse physico-chemical and mechanical properties have been prepared. Materials prepared were examined for mechanical characteristic. Thermal properties were characterized using DSC; temperature modulated DSC; Hi-ResTM TGA and DMA. Viscosity measurements were employed for molecular characterization. © 2008 Elsevier Ltd. All rights reserved;
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页码：1733 / 1742
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