Chromium, tungsten and vanadium sediment-porewater geochemistry under oxic and anoxic redox conditions: Implication for their remobilization

Global chromium (Cr), tungsten (W), and vanadium (V) cycles are emerging concerns due to their toxicities to ecosystems. However, a comprehensive understanding of their geochemical reactions and controls at the sediment-water interface remains largely unknown. This knowledge gap hinders the assessment of their potential remobilization in Earth's surface environments threatened by hypoxic conditions. We collected pore water and sediment samples from the undisturbed Castle Lake, situated in the Klamath-Siskiyou Mountains of northern California, USA, to investigate the geochemical controls responsible for the fixation and release of Cr, W, and V under redox transitions from oxia to anoxia during early diagenesis. The results show that, under oxic conditions, authigenic Cr, W, and V ratios in porewater account for approximately 4.7 %, © 2024 Elsevier B.V.