Hydrogen-Assisted Mg Intercalation into 2H-TaS2

被引：0

作者：

Fujioka, Masaya ^{[1
,2
]}

Zagarzusem, Khurelbaatar ^{[3
]}

Iwasaki, Suguru ^{[4
]}

Sharma, Aman ^{[1
]}

Watanabe, Konosuke ^{[1
]}

Nakayama, Rei ^{[1
]}

Momai, Mizuki ^{[1
]}

Yamaguchi, Yuki ^{[1
]}

Shimada, Hiroyuki ^{[1
]}

Nomura, Katsuhiro ^{[1
]}

Mizutani, Yasunobu ^{[1
]}

Sumi, Hirofumi ^{[1
]}

Tanaka, Masashi ^{[5
]}

Jeem, Melbert ^{[6
]}

Hattori, Mineyuki ^{[7
]}

Saitoh, Hiroyuki ^{[8
]}

Ozaki, Toshinori ^{[9
]}

Nagao, Masanori ^{[10
]}

Nagashima, Kazuki ^{[2
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Innovat Funct Mat Res Inst, Nagoya, Aichi 4638560, Japan

[2] Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido 0010020, Japan

[3] Mongolian Univ Sci & Technol, Sch Informat & Commun Technol, Dept Elect, Ulaanbaatar 14191, Mongolia

[4] Tokyo Univ Sci, Fac Engn, Dept Ind Chem, Katsushika, Tokyo 1258585, Japan

[5] Kyushu Inst Technol, Grad Sch Engn, Kitakyushu, Fukuoka 8048550, Japan

[6] Hokkaido Univ, Fac Engn, Sapporo, Hokkaido 0608628, Japan

[7] Natl Inst Adv Ind Sci & Technol, Natl Metrol Inst Japan, Res Inst Mat & Chem Measurement, Tsukuba, Ibaraki 3058565, Japan

[8] Natl Inst Quantum Sci & Technol, Sayo, Hyogo 6795148, Japan

[9] Kwansei Gakuin Univ, Sch Engn, Sanda, Hyogo 6691330, Japan

[10] Univ Yamanashi, Ctr Crystal Sci & Technol, Kofu, Yamanashi 4000021, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2024年

基金：

日本科学技术振兴机构; 日本学术振兴会;

关键词：

SUPERCONDUCTIVITY; MAGNESIUM; CRYSTAL; STATE;

D O I：

10.1021/jacs.4c07294

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intercalation reactions are highly dependent on the electronic and structural relationships between host and guest materials. It is difficult for divalent ions, such as Mg, to undergo intercalation reactions compared with monovalent cations. However, further development of synthetic techniques for controlling divalent ions is strongly demanded to advance applied chemistry and fundamental physics. In this study, the cointercalation of Mg and H into the transition-metal chalcogenide TaS2 was utilized to obtain bulk polycrystalline Mg x H y TaS2. Introduced H can be extracted via postannealing at approximately 400 degrees C without altering the crystal structure. This study clarified the relationship between superconducting properties and electronic carrier density from the perspectives of calculations and experiments, along with the advantages of using hydride as a multivalent intercalation reaction.

引用

页码：34324 / 34332

页数：9

共 50 条

[1] INTERCALATION OF GASES INTO 2H-TAS2
ACRIVOS, JV
DELIOS, C
BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1976, 21 (01): : 91 - 91
[2] KINETICS OF THE LITHIUM INTERCALATION OF 2H-TAS2
MUHLBERGER, R
BUTZ, T
LERF, A
PHYSICA B & C, 1981, 105 (1-3): : 218 - 222
[3] AMMONIA INTERCALATION IN 2H-TAS2 AND 1T-TAS2
DIEBOLT, LA
GLAUNSINGER, WS
MCKELVY, MJ
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 201 : 372 - INOR
[4] INTERCALATION REACTION-KINETICS - A TDPAC STUDY OF 2H-TAS2 INTERCALATION
BUTZ, T
HUBLER, A
BESENHARD, JO
LERF, A
BIBERACHER, W
NUOVO CIMENTO DELLA SOCIETA ITALIANA DI FISICA D-CONDENSED MATTER ATOMIC MOLECULAR AND CHEMICAL PHYSICS FLUIDS PLASMAS BIOPHYSICS, 1983, 2 (06): : 1971 - 1976
[5] INTERCALATION OF AMINO-ACIDS AND POLYPEPTIDES INTO 2H-TAS2
CHAPELA, VM
PARRY, GS
NATURE, 1979, 281 (5727) : 134 - 135
[6] METASTABLE CONFIGURATIONS DURING LITHIUM INTERCALATION INTO 2H-TAS2
BUTZ, T
LERF, A
BESENHARD, JO
REVUE DE CHIMIE MINERALE, 1984, 21 (04): : 556 - 587
[7] SHUBNIKOV-DEHAAS OSCILLATIONS IN INTERCALATION COMPOUNDS OF 2H-TAS2
BIBERACHER, W
JOSS, W
VANRUITENBEEK, JM
LERF, A
PHYSICAL REVIEW B, 1989, 40 (01): : 115 - 118
[8] Torque measurements on methylene blue intercalation compounds of 2H-TaS2
Schlicht, A
Lerf, A
Biberacher, W
SYNTHETIC METALS, 1999, 102 (1-3) : 1483 - 1484
[9] STRUCTURE OF 2H-TAS2
MEETSMA, A
WIEGERS, GA
HAANGE, RJ
DEBOER, JL
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 1598 - 1599
[10] ELECTRONIC-STRUCTURES OF INTERCALATION COMPLEXES OF THE LAYERED COMPOUND 2H-TAS2
GUO, GY
LIANG, WY
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1987, 20 (27): : 4315 - 4334

← 1 2 3 4 5 →