Tape-casting performance of ethanol slurries for the processing of textured PMN-PT ceramics from nanocrystalline powder

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作者
Amorín, Harvey [1 ]
Santacruz, Isabel [2 ]
Holc, Janez [3 ]
Thi, Mai Pham [4 ]
Kosec, Marija [3 ]
Moreno, Rodrigo [2 ]
Algueró, Miguel [1 ]
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[1] Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, 28049 Madrid, Spain
[2] Instituto de Cerámica y Vidrio, CSIC, Cantoblanco, 28049 Madrid, Spain
[3] Institute Jozef Stefan, 1000 Ljubljana, Slovenia
[4] Thales Research and Technology France, 91404 Orsay Cedex, France
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The rheological behavior and tape-casting performance of ethanol-based Pb(Mg1/3Nb2/3)O3-PbTiO3 (PMN-PT) slurries is studied. A nanocrystalline powder obtained by mechanochemical activation was used. Suspensions were prepared up to solid contents of 32 vol%; significantly higher than those usually reported for nonaqueous systems. The feasibility of replacing toxic solvents commonly used for tape casting of functional ferroelectric materials; often toluene; with ethanol is demonstrated. The density; phases and microstructure of the green tapes and sintered ceramics are presented. Cube-shaped templates were successfully aligned during the tape casting for the processing of 〈001-textured PMN-PT ceramics by templated grain growth. An effect of the lamination of tape stacks on the template orientation is described. © 2009 The American Ceramic Society;
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页码:996 / 1001
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    Amorin, Harvey
    Santacruz, Isabel
    Holc, Janez
    Thi, Mai Pham
    Kosec, Marija
    Moreno, Rodrigo
    Alguero, Miguel
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