Differential scanning calorimetry analysis of the thermal treatment of ternary mixtures of ethylene vinyl acetate, polyethylene, and azodicarbonamide

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作者
Reyes-Labarta, J.A. [1 ]
Marcilla, A. [1 ]
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[1] Department of Chemical Engineering, University of Alicante, Apartado 99, Alicante E-03080, Spain
来源
Journal of Applied Polymer Science | 2008年 / 110卷 / 05期
关键词
The different transitions and reactions involved in the thermal processing of ternary ethylene vinyl acetate (EVA)-polyethylene (PE)-azodicarbonamide (ADC) mixtures with different concentrations of PE and ADC; which was used as a foaming agent; were studied by means of differential scanning calorimetry. The effect of the concentration of PE in the ternary samples was practically linear; which showed an increase in the fusion heat of the PE and the PE domains of the EVA. On the contrary; the mechanism of the thermal decomposition of ADC that the ternary mixtures contained was strongly dependent on its concentration in the sample; which showed clear deviations from linearity. © 2008 Wiley Periodicals; Inc;
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页码:3217 / 3224
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