Amphiphilic, phosphonic acid-capped cadmium selenide quantum dots sensitize a thiomolybdate catalyst for hydrogen production

被引：0
|
作者：
Kosko, Ryan M. [1 ]
Wang, Qirui [1 ]
Peter, Chari Y. M. [1 ]
Phinney, Elizabeth O. [1 ]
Krauss, Todd D. [1 ,2 ]
Bren, Kara L. [1 ]
Matson, Ellen M. [1 ]
机构：
[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
[2] Univ Rochester, Inst Opt, Rochester, NY 14627 USA
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 93期
关键词：
SEMICONDUCTOR NANOCRYSTALS; EVOLUTION; SITES; H-2;
D O I：
10.1039/d4cc03656e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Combining a molecular thiomolybdate cluster, [Mo3S13]2-, with cadmium selenide quantum dots capped with tetraethyleneglycol monomethyl ether phosphonate (TEGPA) ligands results in a highly active photocatalytic system for the production of hydrogen under visible light irradiation. The system reaches turnover numbers exceeding 30 000 and remains active for similar to 200 h.
引用
收藏
页码：13694 / 13697
页数：4
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