Conversion Characterizations of Sulfate Ion and Nitrate Ion in Particulate Matter from Coal-fired Power Plants

被引：3

作者：

Yang L. ^{[1
]}

He Q. ^{[1
]}

Sheng Z.-Y. ^{[1
,2
]}

机构：

[1] School of Environment, Nanjing Normal University, Nanjing

[2] Suzhou Industrial Technology Research Institute of Zhejiang University, Suzhou

来源：

Huanjing Kexue/Environmental Science | 2021年 / 42卷 / 10期

关键词：

Condensable particle matter(CPM); Conversion characterizations; NO[!sub]3[!/sub][!sup]-[!/sup; SO[!sub]4[!/sub][!sup]2-[!/sup; Wet electrostatic precipitator(WESP); Wet flue gas desulfurization(WFGD);

D O I：

10.13227/j.hjkx.202101097

中图分类号：

学科分类号：

摘要：

The particulate matter emitted from coal-fired power plants includes condensable particulate matter(CPM)and filterable particulate matter(FPM). By analyzing the concentration of SO42-and NO3- components of CPM and FPM in the inlet/outlet of wet flue gas desulfurization(WFGD)and the outlet of wet electrostatic precipitator(WESP)from 7 ultra-low emission coal-fired power plants, the variation laws and transformation characteristics were investigated. The results showed that the concentration of SO42- and NO3- of CPM decreased after WFGD, with reduction rates of 43.12%-86.84% and 17.99%-91.58%, respectively, which were different from the conversion trend of FPM. The concentrations of SO42- and NO3- of CPM increased after WESP, with reduction rates of 21.05%-424.65% and 13.51%-298.37%, respectively, which were also different from that of FPM. In the WFGD system, CPM could be transformed into FPM due via condensation and aggregation under the decreasing temperature and increasing of humidity of the flue gas. In the WESP system, SO2 and NO2 in the flue gas combine with water vapor in a redox reaction, which promotes the generation of SO42- and NO3- in CPM through synergistic action. © 2021, Science Press. All right reserved.

引用

页码：4678 / 4686

页数：8

共 36 条

[1] Tie X X, Huang R J, Cao J J, Et al., Severe pollution in China amplified by atmospheric moisture, Scientific Reports, 7, 1, (2017)
[2] Cano M, Vega F, Navarrete B, Et al., Characterization of emissions of condensable particulate matter in clinker kilns using a dilution sampling system, Energy & Fuels, 31, 8, pp. 7831-7838, (2017)
[3] Guo S, Hu M, Zamora M L, Et al., Elucidating severe urban haze formation in China, Proceedings of the National Academy of Sciences of the United States of America, 111, 49, pp. 17373-17378, (2014)
[4] Yang H H, Lee K T, Hsieh Y S, Et al., Filterable and condensable fine particulate emissions from stationary sources, Aerosol and Air Quality Research, 14, 7, pp. 2010-2016, (2014)
[5] Chen X, Yang T, Wang Z F, Et al., Investigating the impacts of coal-fired power plants on ambient PM2.5 by a combination of a chemical transport model and receptor model, Science of the Total Environment, 727, (2020)
[6] Chen J C., Study on the characteristics of inorganic compositions in PM2.5 and source apportionment during haze and non-haze days in Beijing, pp. 2-3, (2018)
[7] Sisler J F, Malm W C., The relative importance of soluble aerosols to spatial and seasonal trends of impaired visibility in the United States, Atmospheric Environment, 28, 5, pp. 851-862, (1994)
[8] Yang L X, Wang D C, Cheng S H, Et al., Influence of meteorological conditions and particulate matter on visual range impairment in Jinan, China, Science of the Total Environment, 383, 1-3, pp. 164-173, (2007)
[9] Jiang D H, Su Y J., The haze pollution controlling requires emission concentration reducing of condensable particulates first, Electric Power Environmental Protection, 34, 4, pp. 1-6, (2018)
[10] Cao S A, Su Y J., Mechanism analysis of haze and fog caused by SOx discharged from wet chimney of coal-fired power plant and the measures to govern, North China Electric Power, 8, pp. 54-60, (2017)

← 1 2 3 4 →