Experimental and simulated study of ammonia blending with DME steam reformed and cracked gases under lean-burn condition

被引:1
|
作者
Zhang, Xuanrui [1 ]
Meng, Xiangyu [1 ]
Zhu, Wenchao [1 ]
Long, Wuqiang [2 ]
Bi, Mingshu [1 ]
机构
[1] Dalian Univ Technol, Sch Chem Engn, Dalian 116024, Liaoning, Peoples R China
[2] Dalian Univ Technol, Inst Internal Combust Engine, Dalian 116024, Liaoning, Peoples R China
基金
中国国家自然科学基金;
关键词
DME steam reforming and cracking; Ammonia combustion; Visualization measurements; Lean-burn condition; NO x generation; DIMETHYL ETHER; PERFORMANCE-CHARACTERISTICS; HYDROGEN-PRODUCTION; CATALYSTS;
D O I
10.1016/j.ijhydene.2024.10.177
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Dimethyl ether (DME) steam reforming (SR) and cracking (CR) can not only achieve on-line production of hydrogen (H2) and methane (CH4) but also increase fuel energy. The ammonia blending with DME-SR or DMECR gases is an effective method to enhance the reactivity of ammonia combustion. This paper aims to compare the effects of DME-SR and DME-CR on combustion and emissions under lean-burn condition. In the constant volume combustion chamber (CVCC) experiments, the in-chamber pressure and flame propagation process were measured for NH3/H2 and NH3/CH4 blends, and NO emissions were visualized by chemiluminescence. A threedimensional (3D) model was established with validation by the experimental data. Based on this model, the effects of DME-SR and DME-CR on combustion process and NOx emissions were studied. The results showed that both DME-SR and DME-CR can enhance the ammonia combustion process under lean-burn condition. The case with DME energy ratio 70% and the equivalence ratio of 0.4 for SR (X70ER0.4-SR), and X30ER0.5-SR can achieve faster combustion rates than pure ammonia at ER of 1.0 (X0ER0.9) due to the main reforming product of H2. The ammonia blended with fuels from DME-SR and CR can help to improve the NO emission under lean-burn condition, being lower than X0ER0.9. These findings highlight the advantages of using DME-SR and DME-CR for improving the ammonia combustion. Considering the fuel energy increment, DME-CR could be potential to obtain better fuel economy and emission improvement in real engine application.
引用
收藏
页码:464 / 473
页数:10
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