Acid-catalyzed dehydration of hexoses to 5-hydroxymethylfurfural: Reaction, separation and process coupling

被引：0
|
作者：
Liu M. [1 ]
Jiao Y. [1 ]
Ding L. [1 ]
Li C. [2 ]
He Y. [3 ]
Sun L. [3 ]
Hao Q. [1 ,2 ]
Chen H. [1 ,2 ]
Luo Q. [1 ,2 ]
机构：
[1] International Science and Technology Cooperation Base of MOST for Clean Utilization of Hydrocarbon Resources, Chemical Engineering Research Center of the Ministry of Education for Advanced Use Technology of Shanbei Energy, Shaanxi Research Center of Engine
[2] Shaanxi Key Laboratory for Carbon Neutral Technology, School of Carbon Neutrality (Yulin), Northwest University, Shaanxi, Xi'an
[3] Key Laboratory of Syngas Conversion of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Shaanxi, Xi'an
来源：
Huagong Jinzhan/Chemical Industry and Engineering Progress | 2024年 / 43卷 / 05期
关键词：
5-hydroxymethylfurfural; biomass; catalysis; process intensification; separation;
D O I：
10.16085/j.issn.1000-6613.2023-2099
中图分类号：
学科分类号：
摘要：
5-hydroxymethylfurfural (HMF) is one of paramount platform chemicals for converting biomass into chemicals, fuels and polyester materials. The rational design of efficient catalysts, optimization of catalytic reaction processes, and development of the novel separation and reaction-separation coupling technologies can enhance the comprehensive efficiency in production of HMF, simplify the unit processes, and reduce carbon emissions and energy consumption. In this paper, the state-of-the-art towards catalytic reactions, separation technology and process coupling related during acid-catalyzed dehydration of hexoses to HMF were reviewed from the fundamentals in designing the bifunctional active sites for relay catalysis, integration of tandem reactions, regulation of surface hydrophilicity and hydrophobicity, selection of reaction medium, adsorbent materials, adsorption mechanism and structure-performance relationship, as well as process intensification. The knowledge and learning points gained from this review would be instructive for research communities working on catalysis and separation in biomass utilization. © 2024 Chemical Industry Press Co., Ltd.. All rights reserved.
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页码：2526 / 2543
页数：17
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