Signature of metallic behavior in the metal-organic frameworks M3(hexaiminobenzene)2 (M = Ni, Cu)

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[1] Dou, Jin-Hu
[2] Sun, Lei
[3] Ge, Yicong
[4] Li, Wenbin
[5] Hendon, Christopher H.
[6] Li, Ju
[7] Gul, Sheraz
[8] Yano, Junko
[9] Stach, Eric A.
[10] Dincǎ, Mircea
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Dincǎ, Mircea (mdinca@mit.edu) | 1600年 / American Chemical Society卷 / 139期
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摘要：
The two-dimensionally connected metal- organic frameworks (MOFs) Ni3(HIB)2 and Cu3(HIB)2 (HIB = hexaiminobenzene) are bulk electrical conductors and exhibit ultraviolet-photoelectron spectroscopy (UPS) signatures expected of metallic solids. Electronic band structure calculations confirm that in both materials the Fermi energy lies in a partially filled delocalized band. Together with additional structural characterization and microscopy data, these results represent the first report of metallic behavior and permanent porosity coexisting within a metal-organic framework. © 2017 American Chemical Society.
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