Preparation of SnO2/RGO photoanode and its effect on property of dye-sensitized solar cells

被引:0
|
作者
Qi T. [1 ]
Wang Q. [1 ]
Wang D. [1 ]
Zhang Y. [1 ]
Zheng W. [1 ]
机构
[1] College of Material Science and Engineering, Harbin University of Science and Technology, Harbin
来源
Zheng, Wei (zhengwei1972@sina.com) | 2017年 / Chinese Ceramic Society卷 / 45期
关键词
Dye-sensitised solar cell; Photoanode; Photoelectric property; Reduced graphene oxide; Tin dioxide crystal;
D O I
10.14062/j.issn.0454-5648.2017.01.02
中图分类号
学科分类号
摘要
The SnO2-reduced graphene oxide (RGO) nanocomposites were firstly synthesized by one-pot route and then prepared for the films on FTO (SnO2:F) conductive glass as photoanodes in dye-sensitized solar cells (DSSCs) by a sol-gel method. The DSSCs were assembled with N3-dipped SnO2/RGO photoanode, Pt plate as counter electrodes and I-/I3- as an electrolyte. The SnO2/RGO nanocomposite photoanode was characterized. The photoelectric properties of DSSC were analyzed by volt-ampere (J-U) characteristic curve. The results show that SnO2/RGO nanocomposites as a photoanode in DSSC exhibit better photoelectric properties. The short-circuit current density (Jsc) and the open-circuit voltage (Uoc) of SnO2/RGO-DSSC are 15.56 mA/cm2 and 0.56 V, respectively and the photoelectric conversion efficiency is 4.58% when the mass ratio of GO and SnCl2 2H2O is 0.20. In addition, the effect of SnO2/RGO nanocomposites on the electron transport in the photoanode and PCE of DSSCs were also discussed. © 2017, Editorial Department of Journal of the Chinese Ceramic Society. All right reserved.
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页码:9 / 14
页数:5
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共 16 条
  • [1] Du F., Yang B., Zuo X., Et al., Dye-sensitized solar cells based on low-cost nanoscale SnO<sub>2</sub>@RGO composite counter electrode, Mater Lett, 158, pp. 424-427, (2015)
  • [2] Sun P.P., Zhang X.T., Liu X.P., Et al., Growth of single-crystalline rutile TiO<sub>2</sub> nanowire array on titanate nanosheet film for dye-sensitized solar cells, J Mater Chem, 22, pp. 6389-6393, (2012)
  • [3] Ranjusha R., Lekha P., Subramanian K.R.V., Et al., Photoanode activity of ZnO nanotube based dye-sensitized solar cells, J Mater Sci Technol, 27, 11, pp. 961-966, (2011)
  • [4] Wang J., Ding C., Hu Y., Et al., J Chin Ceram Soc, 42, 7, pp. 862-868, (2014)
  • [5] Diamant Y., Chappel S., Chen S.G., Et al., Core-shell nanoporous electrode for dye sensitized solar cells: the effect of shell characteristics on the electronic properties of the electrode, Coord Chem Rev, 148, pp. 1271-1276, (2004)
  • [6] Nguyen K.H., Son D.Y., Jang I.H., Et al., Hierarchical SnO<sub>2</sub> nanoparticle-ZnO nanorod photoanode for improving transport and life time of photoinjected electrons in dye-sensitized solar cell, ACS Appl Mater Interfaces, 5, pp. 1038-1043, (2013)
  • [7] Uchiyama H., Yukizawa M., Kozuka H., Photoelectrochemical properties of Fe<sub>2</sub>O<sub>3</sub>-SnO<sub>2</sub> films prepared by sol-gel method, J Phys Chem C, 115, pp. 7050-7055, (2011)
  • [8] Luo C.M., He W., Zhou K., Et al., Crystal silicon solar cell thin film material current situation and development trend, Insul Mater, 45, 3, pp. 29-33, (2012)
  • [9] Das S., Kim D.Y., Choi C.M., Et al., Influence of aqueous hexamethy lenetetramine on the morphology of self-assembled SnO<sub>2</sub> nanocrystals, Mater Res Bull, 46, 4, pp. 609-614, (2011)
  • [10] Qi T., Zhang Y., Zheng W., J Chin Ceram Soc, 43, 11, pp. 1525-1530, (2015)