Effect of Mo-Si-B on Sintering Process and Properties of ZrB2 Ultra-high-Temperature Ceramics

被引:0
|
作者
Zhao X. [1 ]
Zhao X. [1 ]
Li Z. [1 ]
Lu X. [1 ]
Shao G. [1 ]
Ma S. [1 ]
Wang H. [1 ]
Zhang R. [2 ]
机构
[1] School of Materials Science and Engineering, Zhengzhou University, Zhengzhou
[2] Zhengzhou University of Aeronautics, Zhengzhou
关键词
Hot pressing; Molybdenum silicon boride; Oxidation resistance; Zirconium diboride;
D O I
10.14062/j.issn.0454-5648.2018.03.11
中图分类号
学科分类号
摘要
Mo, Si and B powders were used as second phase aids to improve the fracture toughness and the oxidation resistance of ZrB2 ceramic. The dense ZrB2-Mo-Si-B ceramic composites were fabricated via hot pressing at 20 MPa and 1 900 ℃ for 1 h due to the in-situ reaction between Mo-Si-B. The flexural strength and fracture toughness of the sintered samples firstly increase, then decrease and further increase with the amount of Mo-Si-B increasing. ZrB2-20% (volume fraction) Mo-Si-B composite has the maximum fracture toughness of (5.55±0.11) MPa·m1/2. ZrB2-30%Mo-Si-B composite has the maximum bending strength of (500±40) MPa. All the sintered samples show a good oxidation resistance due to the glassy phase formed on the surface of composites, preventing the inner-transformation of oxidation. © 2018, Editorial Department of Journal of the Chinese Ceramic Society. All right reserved.
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页码:382 / 387
页数:5
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