Highly piezocatalysis of metal-organic frameworks material ZIF-8 under vibration

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作者
Ruan, Lujie [1 ,2 ]
Jia, Yanmin [1 ]
Guan, Jingfei [1 ,2 ]
Xue, Bei [1 ]
Huang, Shihua [2 ]
Wu, Zheng [3 ]
Li, Guorong [4 ]
Cui, Xiangzhi [4 ]
机构
[1] School of Science, Xi'an University of Posts and Telecommunications, Xi'an,710121, China
[2] College of Physics and Electronic information Engineering, Zhejiang Normal University, Jinhua,321004, China
[3] Xi'an Key Laboratory of Textile Chemical Engineering Auxiliaries, School of Environmental and Chemical Engineering, Xi'an Polytechnic University, Xi'an,710000, China
[4] State Key Laboratory of High Performance Ceramics and Superfine Microstructure, and CAS Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai,200050, China
基金
中国国家自然科学基金;
关键词
Synthesis (chemical) - Metal nanoparticles - Rhodium compounds - Photocatalytic activity;
D O I
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中图分类号
学科分类号
摘要
In this research, metal-organic frameworks ZIF-8 nanoparticles, which is synthesized via the liquid phase method, exhibits the outstanding piezocatalytic performance on Rhodamine B (RhB) dye degradation under vibration. The piezocatalytic degradation ratio of RhB dye (5 mg/L) can reach ∼94.5% after undergoing 90 min vibration. ZIF-8, with the coexistence of cubic phase and monoclinic phase, confirmed from XRD, is piezoelectric in theory, which contributes to the excellent piezocatalytic performance. The main active species, which plays an important role in piezocatalytic process, are the superoxide radicals (· O2-), the positive charges (q+) and the negative charges (q-) on basis of the active species quenching experiment results. The MOF material ZIF-8 is potential in the application field of the highly piezocatalytic dye wastewater degradation under vibration. © 2021 Elsevier B.V.
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