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An Organometallic Cu20 Nanocluster: Synthesis, Characterization, Immobilization on Silica, and click Chemistry
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[1] Cook, Andrew W.
[2] Jones, Zachary R.
[3] Wu, Guang
[4] 1,Scott, Susannah L.
[5] Hayton, Trevor W.
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T.W.H. and A.W.C. thank the National Science Foundation (NSF;
CHE 1361654) for financial support. Z.R.J. and S.L.S. thank the U.S. Department of Energy;
Office of Science;
Office of Basic Energy Sciences;
under the Catalysis Science Initiative (DE-FG-02-03ER15467);
and the NSF PIRE program (OISE-0968399) for financial support. NMR spectra were collected on an instrument supported by a National Institutes of Health Shared Instrumentation Grant (SIG;
1S10OD012077-01A1). ESI mass spectra were acquired at the MRL Shared Experimental Facilities;
supported by the MRSEC Program of the NSF under Award No. DMR 1121053 and a member of the NSF-funded Materials Research Facilities Network. X-ray absorption spectra were acquired at the Stanford Synchrotron Radiation Lightsource;
a Directorate of SLAC National Accelerator Laboratory and an Office of Science User Facility operated for the U.S. Department of Energy;
by Stanford University. A.W.C. thanks the Mellichamp Academic Initiative in Sustainability at UCSB for a summer fellowship;
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