Effect of multifunctional flame retardant tougheners on the flame retardant and mechanical properties of polycarbonates

被引：0
|
作者：
Gao N. [1 ,2 ]
Gao X. [1 ,2 ]
Yan L. [1 ,2 ]
Sang X. [1 ,2 ]
机构：
[1] College of Materials Science and Engineering, North China University of Science and Technology, Tangshan
[2] Key Laboratory of Functional Polymer Materials of Tangshan, Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials, Tangshan
来源：
Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica | 2024年 / 41卷 / 05期
关键词：
ACR; flame retardancy; mechanical properties; phosphorus-silicon synergy; polycarbonate; toughening;
D O I：
10.13801/j.cnki.fhclxb.20230922.002
中图分类号：
学科分类号：
摘要：
In order to balance the effect of flame retardant modification and mechanical modification of polycarbonate (PC), the flame retardant toughening agent with silicone-phosphorus-containing acrylate core-shell structure (ACR) prepared by seed emulsion polymerization was used to modify PC materials in this paper. When 4wt%ACR was added to PC, the limiting oxygen index (LOI) of 4%ACR/PC could reach 31.7%, the vertical combustion test reached UL-94 V-0 level, and the cone calorimeter test showed that the combustion heat release and smoke density were reduced by 43.2% and 20.5%, respectively. At the same time, the tensile strength of 4%ACR/PC was similar to that of pure PC, and the impact strength was increased by 9.4%. Thermogravimetric-infrared spectroscopy, Raman spectroscopy and post-combustion residue scanning electron microscopy analysis showed that the flame retardant effect was mainly due to the synergistic effect of phosphorus-silicon and the catalytic charring effect of phosphorus on PC. The impact cross-section SEM images showed that the toughening effect is reflected in the fact that the ACR core layer silicone rubber can absorb impact energy and inhibit or terminate the generation of cracks. © 2024 Beijing University of Aeronautics and Astronautics (BUAA). All rights reserved.
引用
收藏
页码：2395 / 2403
页数：8
相关论文
共 26 条
  • [1] LIU Junwei, GAO Shanjun, SHEN Chunhui, Et al., Flame-retardation synergism and dynamic mechanical properties of polycarbonate/ASA composites modified by silicon and organo-phosphate containing flame retardants, Acta Materiae Compositae Sinica, 35, 11, pp. 3062-3072, (2018)
  • [2] NI P, FANG Y Y, QIAN L J, Et al., Flame-retardant behavior of a phosphorus/silicon compound on polycarbonate, Journal of Applied Polymer Science, 135, 6, (2018)
  • [3] YANG Y Y, LIU J, CAI X F., Antagonistic flame retardancy between hexakis(4-nitrophenoxy) cyclotriphosphazene and potassium diphenylsulfone sulfonate in the PC system, Journal of Thermal Analysis and Calorimetry, 126, 2, pp. 571-583, (2016)
  • [4] HOU S J, ZHANG Y J, JIANG P K., Phosphonium sulfonates as flame retardants for polycarbonate, Polymer Degradation and Stability, 130, pp. 165-172, (2016)
  • [5] ZHANG X Y, ZHANG D L, ZHANG W C, Et al., Flame retardant polycarbonate with ultralow loading 1, 3-benzenedi-sulfonate, Polymer Degradation and Stability, 214, (2023)
  • [6] WAWRZYN E, SCHARTEL B, KARRASCH A, Et al., Flame-retarded bisphenol A polycarbonate/silicon rubber/ bisphenol A bis(diphenyl phosphate): Adding inorganic additives, Polymer Degradation and Stability, 106, pp. 74-87, (2014)
  • [7] WU X, QIN Z, ZHANG W, Et al., KCl nanoparticles-loaded octaphenylsilsesquioxane as an efficient flame retardant for polycarbonate, Reactive and Functional Polymers, 177, (2022)
  • [8] STATLER D, STAJDUHAR E, GUPTA R K., Flame retardancy of polycarbonate upon repeated recycling, Journal of Fire Sciences, 26, 4, pp. 331-350, (2008)
  • [9] SUN C C, ZHANG W, CUI Y H, Et al., Synthesis of phosphazene-triazine bi-base sulfonate and its applications in flame-retardant modified polycarbonate, Journal of Applied Polymer Science, 139, 21, (2022)
  • [10] WANG X X, ZHANG W C, QIN Z L, Et al., Optically transparent and flame-retarded polycarbonate nanocomposite based on diphenylphosphine oxide-containing polyhedral oligomeric silsesquioxanes, Composites Part A: Applied Science and Manufacturing, 117, pp. 92-102, (2019)
123