Characteristics and Implication of Carbon and Oxygen Isotopes in Ga-Rich Manganese-Bearing Rock Series in Dongping, Guangxi

被引:1
|
作者
Li Q. [1 ]
Yi H. [1 ,2 ]
Xia G. [1 ]
Ji C. [3 ]
Jin F. [1 ]
机构
[1] Institute of Sedimentary Geology, Chengdu University of Technology, Chengdu
[2] State Key Laboratory of Oil and Gas Reservoir Geology and Exploration, Chengdu University of Technology, Chengdu
[3] Chinese Academy of Geological Sciences, Beijing
来源
关键词
Carbon and oxygen isotopes; Ga anomaly; Manganese deposit; Ore deposits;
D O I
10.3799/dqkx.2017.530
中图分类号
学科分类号
摘要
Recently, an unusually high content of Ga was discovered in manganese carbonate deposits of the Beisi Formation in Dongping area, Guangxi. The content of Ga is between 5.16×10-6 and 82.80×10-6, and the average content is 33.76 ×10-6, which reaches the industrial grade of Ga. But, to date Ga is not extracted from manganese deposits. In order to deepen the understanding of this phenomenon, the results of carbon and oxygen isotopes in the Ga-rich manganese-bearing rock series are reported in this paper. The results show that δ13CPDB of ores and host rocks are -6.40‰ to -2.20‰ and -8.90‰ to 0.90‰, respectively; δ18OPDB of ores and host rocks are -9.00‰ to -7.90‰ and -9.90‰ to -3.90‰, respectively. The results of the research show that (1) organic matter participates in the formation of manganese carbonate; (2) the Ga-rich manganese-bearing rock series belong to hydrothermal sedimentary genesis, and the source of Ga is related to seafloor hydrothermal activity; (3) seafloor hydrothermal activity plays a key role in the mineralization process of this Ga-rich manganese-bearing rock series, it directly or indirectly provides a large amount of organic matter to formation of manganese carbonates, on the other hand, it brought a lot of Ga that can be adsorbed by manganese oxides or hydroxide, marine organisms (mostly hydrothermal microorganism), then Ga concentrated in manganese-bearing rock series by complex diagenesis and mineralization. © 2017, Editorial Department of Earth Science. All right reserved.
引用
收藏
页码:1508 / 1518
页数:10
相关论文
共 73 条
  • [1] An C.B., Feng Z.D., Barton L., Dry or Humid? Mid-Holocene Humidity Changes in Arid and Semi-Arid China, Quaternary Science Reviews, 25, 3-4, pp. 351-361, (2006)
  • [2] Anikeeva L.I., Kazakova V.E., Gavrilenko G.M., Ferromanganese Crust Formations of the West Pacific Transition Zone. Vestnik KRAUNTs, Nauki o Zemle, 11, 1, pp. 10-31, (2008)
  • [3] Baturin G.N., Dobretsova I.G., Dubinchuk V.T., Hydrothermal Manganese Mineralization in the Peterbourgskoye Ore Field (North Atlantic), Oceanology, 54, 2, pp. 222-230, (2014)
  • [4] Baturin G.N., Dubinchuk V.T., Rashidov V.A., Distribution of Microelements in Ferromanganese Crusts of the Sea of Okhotsk, Doklady Earth Sciences, 440, 1, pp. 1291-1297, (2011)
  • [5] Baturin G.N., Dubinchuk V.T., Rashidov V.A., Ferromanganese Crusts from the Sea of Okhotsk, Oceanology, 52, 1, pp. 88-100, (2012)
  • [6] Baturin G.N., Dubinchuk V.T., Savels'ev D.P., Et al., Ferromanganese Crusts on the Bottom of the Bering Sea, Doklady Earth Sciences, 435, 1, pp. 1478-1482, (2010)
  • [7] Benezeth P., Diakonov I.I., Pokrovski G.S., Et al., Gallium Speciation in Aqueous Solution. Experimental Study and Modelling: Part 2. Solubility of α-GaOOH in Acidic Solutions from 150 to 250℃ and Hydrolysis Constants of Gallium (III) to 300℃, Geochimica et Cosmochimica Acta, 61, 7, pp. 1345-1357, (1997)
  • [8] Boni M., Parente G., Bechstadt T., Et al., Hydrothermal Dolomites in SW Sardinia (Italy): Evidence for a Widespread Late-Variscan Fluid Flow Event, Sedimentary Geology, 131, 3-4, pp. 181-200, (2000)
  • [9] Chen J., Wang H.N., Geochemistry, (2004)
  • [10] Coleman M., Fleet A., Donson P., Preliminary Studies of Manganese-Rich Carbonate Nodules from Leg 68, Site 503, Eastern Equatorial Pacific, Initial Reports of the Deep Sea Drilling Project, 68, pp. 481-489, (1982)