Influence of ZnO on Luminescent Properties of CdSxSe1-x Quantum Dot Silicate Glass

被引：0
|
作者：
Luo T. [1 ]
Jiang H.-Y. [1 ]
Yang Y.-T. [1 ]
机构：
[1] College of Materials Science and Engineering, Wuhan University of Technology, Wuhan
来源：
Faguang Xuebao/Chinese Journal of Luminescence | 2017年 / 38卷 / 09期
关键词：
CdS[!sub]x[!/sub]Se[!sub]1-x[!/sub] quantum dots; Glass; Luminous performance; ZnO;
D O I：
10.3788/fgxb20173809.1155
中图分类号：
学科分类号：
摘要：
CdS, Se, Zn powder and glass matrix were used as raw material to prepare the CdSxSe1-x quantum dots silicate glass by using co-melting method. The effect of ZnO content on the microscopic structure and luminescent properties of CdSxSe1-x quantum dots silicate glass were studied. Experimental results indicate that ZnO can significantly influence the luminescence properties of CdSxSe1-x quantum dots glass. The results of ultraviolet-visible absorption spectrum and fluorescence spectrum analysis show that the CdSxSe1-x quantum dots are in a strong confined area, which lead to a strong belt edge exciton emission phenomenon, proving that the quantum size effect of quantum dots is obvious under the excitation of 470 nm blue light. When the mole fraction of ZnO is 13%, the PL spectrum peak is the strongest, and the half width of peak is the narrowest. © 2017, Science Press. All right reserved.
引用
收藏
页码：1155 / 1160
页数：5
相关论文
共 18 条
  • [1] Xu Z.S., Chang C., Ma D.W., Preparation and Optical characterization of PbSe quantum dot-doped silicate glass with high concentration, Acta Opt. Sinica, 32, 9, (2012)
  • [2] Jia R., Jiang D.S., Tan P.H., Et al., Photoluminescence study of CdSe<sub>x</sub>S<sub>1-x</sub> quantum dots in a glass spherical microcavity, Chin. Phys. Lett., 18, 10, pp. 1350-1352, (2001)
  • [3] Li H., Wang C.B., Peng Z.J., Et al., A review on the synthesis methods of CdSeS-Based nanostructures, J. Nanomater., 2015, pp. 1-16, (2015)
  • [4] Huang G.F., Lu A.X., Research progress of semiconductor quantum dots glasses, Mater. Rev., 20, 5, pp. 30-32, (2006)
  • [5] Yang F.J., SPS Preparation of Pb(Cd)S Quantum Dots Glass and Its Properties, (2014)
  • [6] Ma D.W., Zhang Y.N., Xu Z.S., Et al., Influence of intermediate ZnO on the crystallization of PbSe quantum dots in silicate glasses, J. Am. Ceram. Soc., 97, 8, pp. 2455-2461, (2014)
  • [7] Cheng F.Y., Preparation and Luminescence Properties of CdSSe Quantum Dots Glass Ceramics, (2014)
  • [8] Taiapin D.V., Lee J.S., Kovalenko M.V., Et al., Prospects of colloidal nanocrystals for electronic and optoelectronic applications, Chem. Rev., 110, 1, pp. 389-458, (2010)
  • [9] Cheng C., Jiang H.L., Ma D.W., Et al., An optical fiber glass containing PbSe quantum dots, Opt. Commum., 284, 19, pp. 4491-4495, (2011)
  • [10] Chang J., Liu C., Heo J., Optical properties of PbSe quantum dots doped in borosilicate glass, J. Non-Cryst. Solids, 355, 37-42, pp. 1897-1899, (2009)
12