Oxidant-free conversion of primary amines to nitriles

被引：0
|
作者：
Tseng, Kuei-Nin T. [1 ]
Rizzi, Andrew M. [1 ]
Szymczak, Nathaniel K. [1 ]
机构：
[1] Department of Chemistry, University of Michigan, Ann Arbor, MI 48109, United States
来源：
Journal of the American Chemical Society | 2013年 / 135卷 / 44期
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摘要：
An amide-derived NNN-Ru(II) hydride complex catalyzes oxidant-free, acceptorless, and chemoselective dehydrogenation of primary and secondary amines to the corresponding nitriles and imines with liberation of dihydrogen. The catalyst system tolerates oxidizable functionality and is selective for the dehydrogenation of primary amines (-CH2NH2) in the presence of amines without α-CH hydrogens. © 2013 American Chemical Society.
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页码：16352 / 16355
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