Electrostatic Interaction of Dielectric Particles in Electrolyte Solution

被引:0
|
作者
Grashchenkov, S. I. [1 ]
机构
[1] Pskov State Univ, Pskov 180000, Russia
关键词
Poisson-Boltzmann equation; two charged microparticles; charge constancy; colloidal particles; POISSON-BOLTZMANN EQUATION; SPHERICAL COLLOIDAL PARTICLES; FREE-ENERGY; STABILITY; FORCES;
D O I
10.1134/S1061933X24600659
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Poisson-Boltzmann equation has been employed to consider the electrostatic interaction between two charged dielectric spherical particles in a solution of a symmetric electrolyte. The interaction forces between the particles of the same radius have been calculated by the finite element method under the condition of uniform charge distribution on their surfaces in the absence of an external field. The dependence of the electrostatic repulsion forces between the particles on the magnitude of the particle charges and the dielectric permittivities of the particle materials and the ambient medium has been analyzed.
引用
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页码:690 / 698
页数:9
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